By Jie Jack Li
In this 5th version of Jack Jie Li's seminal "Name Reactions", the writer has extra twenty-seven new identify reactions to mirror the hot advances in natural chemistry. As in earlier variants, each one response is delineated through its specific step by step, electron-pushing mechanism and supplemented with the unique and the most recent references, specifically from evaluation articles. Now with addition of many manmade purposes, this ebook is not just an vital source for complex undergraduate and graduate scholars, yet can be an outstanding reference e-book for all natural chemists in either and academia.
Unlike different books on identify reactions in natural chemistry, identify Reactions, a set of certain response Mechanisms and artificial purposes specializes in the response mechanisms. It covers over 320 classical in addition to modern identify reactions.
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During this 5th version of Jack Jie Li's seminal "Name Reactions", the writer has further twenty-seven new identify reactions to mirror the new advances in natural chemistry. As in past versions, every one response is delineated by means of its distinctive step by step, electron-pushing mechanism and supplemented with the unique and the newest references, in particular from evaluate articles.
Additional resources for Name Reactions: A Collection of Detailed Reaction Mechanisms
J. Heterocyc1. Chem. 1993,30, I. ; Chandrasekhar, S. Tetrahedron Lett. 2000,41,7235. Barman, D. ; Thakur, A. ; Sandhu, J. S. Chem. Lett. 2000, 1196. Khodaei, M. ; Meybodi, F. ; Salehi, P. Synth. Commun. 2001, 31, 2047. 26 Beirut reaction Synthesis of quinoxaline-l A-dioxide from benzofurazan oxide. 0 0- O:NN LPh I ~ + +'0 -... o / Et3N: - 0 Et3N .. Ph o C0 2 Et .. (X ~ I OH I NHCOPh -0 .. 0 OH I (X ~ +~ OH I 9' .. CHO N I o COPh --..... N~OH) (X I ~=_ ~ N/. I o COPh .. 27 References 1. 2. 3. 4.
H0l:) H - H+ H+ HOU .. 1 ,-CI ()C9H2 SN2 .. ()CI ::::::..... 1 + H2 O References 1. 2. Blanc, G. Bull. Soc. Chim. Fr. 1923,33,313. Franke, A. ; Traber, W. Helv. Chim. Acta 1975, 58,283. ,~OH N References 1. 2. 3. 4. Bell, T. ]. Org. Chem. 1986, 51,764. Newkome, G. ; Theriot, K. ; Gupta, V. ; Fronczek, F. ; Baker, G. R. ]. Org. Chem. 1986, 54, 1766. ; Schmidt, E. Arch. Pharm. 1991, 324, 359. ; Haddon, H. ; Balavoine, G. G. A. Synth. Commun. 1995, 25,629. 40 Boger pyridine synthesis Q H Hetero-Diels-Alder reaction Retro-Diels-Alder reaction, - N2 • ~ H~ o o • :B -N References 1.
Heterocycles 2001,55,589. 37 Blaise reaction ~-Ketoesters from nitriles and a-haloesters using Zn. 1. Zn, THF, reflux R-CN + nucleophilic addition workup . - References 1. 2. 3. 4. 5. 6. 7. 8. 9. Blaise, E. E. C. R. Hebd. Seances Acad. Sci. 1901, 132,478. Kagan, H. -H. Bull. Soc. Chim. Fr. 1966, 1819. Hannick, S. ; Kishi, Y. J. Org. Chem. 1983, 48,3833. ; Kobayashi, K. Tetrahedron Lett. 1982, 23,1597. Krepski, L. ; Lynch, L. ; Heilmann, S. ; Rasmussen, J. K. Tetrahedron Lett. 1985,26,981. Beard, R.