By Arthur Martell, Robert M. Smith
Over the earlier fifteen years the fee on Equilibrium info of the Analytical department of the I nter nationwide Union of natural and utilized Chemistry has been sponsoring a noncritical compilation of steel complicated formation constants and comparable equilibrium constants. This paintings was once large in scope and led to the booklet of 2 huge volumes of balance Constants through the Chemical Society (London). the 1st quantity, edited through L. G. Si"en (for inorganic ligands) and by way of A. E. Marte" (for natural ligands), was once released in 1964 and coated the literature via 1962. the second one quantity, subtitled complement No.1, edited via L. G. Si"en and E. Hogfeldt (for inorganic ligands) and by means of A. E. Marte" and R. M. Smith (for natural ligands), used to be released in 1971 and lined the literature as much as 1969. those huge compilations tried to hide a" papers within the box concerning steel complicated equilibria (heats, entropies, and loose energies). because it used to be the coverage of the fee in the course of that interval to prevent judgements about the caliber and reliability of the broadcast paintings, the compilation might usually comprise from ten to 20 values for a unmarried equilibrium consistent. in lots of situations the values might fluctuate via one or perhaps orders of significance, therefore not easy readers who desired to use the knowledge with out doing the wide literature research essential to ascertain the right kind price of the consistent in question.
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Extra resources for Critical Stability Constants: Inorganic Complexes
0 Bibliography: H+ 57A,59Ab,62IC,65SS,66BK,70CJ,71P 2 Fe + ,Fe 3+ 65WC Co 2+ 6SIW Other references: OOM,OOT,00WC,25HW,30RH, 31BDa,32Br,47R,50H,50VK,53S,54W,55F, 56N,56PJ,56SM,57TM,5SSWa,60MJ,61Mb, Ni 2+ 59FSa,63CI,6SKM,71IJ,71PH,74P 61MB,63AS,63PB,64GH,64VHa,65FK,67BP, Cu+ 67IJ,71PK,74KH 67ZF,6SAD,6SEP,69KH,71DG,72CD,72HF, Ag+ 56KSa,65ZP,67AD,67IJ,72GC Hg2 2+ 29B CH3Hg+ 65SS Pd 2+ 67IW Zn 2+ 65IC,71IJ,71P Cd 2+ 44L,66Gb,71IJ,71P Hg 2+ 57A,5SNC,59NH,65CI,71IJ 72P,74Kc II. L co 2+ . L Equilibrium 4 Log K 2r, 1.
10 v 180, 1. 7 Bibliography: H+ Mg 2+ Ca 2+ 14MR,25MM,28SH,35MB,35SM,35W,37P,38CH, Pb 2+ 41HS,43HD,46N,57MS,58FN,58NR,59Ea,60GL, Other references: 28RS,35KA,59FB,61NM 00Bc,03AC,07P,09SL,11AV, 61NM,71Nb, 73DH, 73MC 13AP,14W,15J,17SL,220,23M,26HB,29K, 41G,62H,63Ha,74RL 30M,39HJ,42N,42Na,46KD,50M,51M,52Lb, 29FJ,35HR,37BH,41G,46Na,62GT,68La,70Lb, 52Sf,55MB,56BC,57Sa,57Sb,57Sc,58LG, 74JL,74RL 35KA 58MG,58ML,58VG,59E,59Kb,59KS,59U, Sr 2+ 2+ Ba 35KA,46Na,73BS y 3+_Yb 3+ 66JH 2+ Mn 35KA,63H,70GK Fe 2+,Ni 2+,Zn 2+,Cd 2+ 35KA Co 2+ 67B Cu 2+ 35KA,58Sb,59FB,68SRG Ag+ 27WB Hg2 2+ 29B 60BG,60BK,60R,61GM,61GT,61PK,62GM, 62PNN,62SH,62WS,63E,63MG,63R,63SR, 64FD,65BBa,65GSS,66BT,67Ba,68B,68BB, 68Na,69Bc,69H,69NR,70HKS,71Na,72MV, 720S D.
0; 20-40°, 0 Bibliography: H+ K+ 61Tb,62Sa,64HR,64T,65La,66TJ,67LB, Hg2 2+ Tl+ 68HSa,68LJ,70Lc,72AJ,72LL Other references: 34NR,53TK,55DP,58Hb,58HN,58SM,60BC, 31BR Ba2+ 43BR Th 4+ , Np 22+ ' Fe 3+ Cu 2+ 51PC ° Ag+ 29B 53Sa 05AS,07S,10BS,23B,24B, 28H,28Ja,28S,32BR,32HJ,36E,41SW,42D, 42KP,43BR,51K,53PH,54TK,56C,57HN, 72BT 35CM,41M,54Pa 58KGL,60SS,63EK,63K,64MKc,66E,66HN, 66MB,67JJ,68PW,73AB II. 0) (11. 9) (-ZO) Bibliography: H+ 58SM,63RC,63AA,64SS,68ASb,68SS,76BM CaZ+,Pb Z+ 58MH Ag+ 54Pb,56MH Other references: 31N,34BG,53PH,54IK, 56DZc,57DB,58SS,58YA,60Da,61Sd, 61Ta,63CK,63F,63LZ,63SBa,63YR,65C, 65CO,67Ab,67HS,67VDa,68DK,69BW, 74JJ B.