Download Cleavage of Carbon-Carbon Single Bonds by Transition Metals by Masahiro Murakami, Naoto Chatani PDF

By Masahiro Murakami, Naoto Chatani

Edited by means of major specialists and pioneers within the box, this can be the 1st up to date booklet in this sizzling topic.
The authors offer artificial chemists with diverse easy methods to turn on carbon-carbon sigma bonds in natural molecules promoted via transition steel complexes. They clarify the elemental ideas and techniques for carbon-carbon bond cleavage and spotlight lately constructed man made protocols in line with this system. In so doing, they conceal cleavage of C-C bonds in strained molecules, reactions regarding removal of carbon dioxide and ketones, reactions through retroallylation, and cleavage of C-C bonds of ketones and nitriles.
the result's a great info resource for researchers in academia and operating within the box of man-made natural chemistry, whereas both serving as supplementary examining for complex classes in organometallic chemistry and catalysis.

Show description

Read Online or Download Cleavage of Carbon-Carbon Single Bonds by Transition Metals PDF

Best materials & material science books

Materials for engineering

This 3rd version of what has turn into a contemporary vintage provides a full of life evaluation of fabrics technological know-how that's excellent for college kids of structural engineering. It includes chapters at the constitution of engineering fabrics, the decision of mechanical houses, metals and alloys, glasses and ceramics, natural polymeric fabrics and composite fabrics.

Atlas of Fatigue Curves

Comprises greater than 500 fatigue curves for commercial ferrous and nonferrous alloys. additionally encompasses a thorough clarification of fatigue checking out and interpretation of try out effects. each one curve is gifted independently and comprises an evidence of its specific significance. The curves are titled by means of common commercial designations (AISI, CDA, AA, and so on.

Perovskites and Related Mixed Oxides: Concepts and Applications

This complete guide and prepared reference information the entire major achievements within the box of perovskite-based and comparable mixed-oxide fabrics. The authors speak about, in an independent demeanour, the potentials in addition to the demanding situations with regards to their use, hence providing new views for study and improvement on either a tutorial and commercial point.

Transition Metal-Catalyzed Heterocycle Synthesis via C-H Activation

Reflecting the super progress of this scorching subject lately, this e-book covers C-H activation with a spotlight on heterocycle synthesis. As such, the textual content offers common mechanistic points and offers a complete evaluation of catalytic reactions within the presence of palladium, rhodium, ruthenium, copper, iron, cobalt, and iridium.

Extra resources for Cleavage of Carbon-Carbon Single Bonds by Transition Metals

Sample text

36 Intramolecular cross-coupling yielding spirocyclic product 41. 37 Cross-coupling of cyclopropanol 42 and acyl chlorides. 38) [55]. 38 Rearrangement of 1-(1-alkynyl)cyclopropanol to 2-cyclopentenone. 8 Vinylcyclopropanes cyclopropane to produce metallacyclohexanone. Reductive elimination followed by liberation of the dicobalt species formed 3-substituted cyclopentenone. 8 Vinylcyclopropanes There are numerous reports on transition-metal-catalyzed reactions of vinylcyclopropanes (VCPs). Because there are several excellent reviews available on this subject [56], only typical examples and advances in the last decade are highlighted.

2006) J. Am. Chem. , and Oshima, K. (2008) Org. , and Oshima, K. (2006) Org. , and Oshima, K. (2011) Angew. Chem. Int. , 50, 3294–3298; See 63c For Zn. , and Oshima, K. (2008) J. Am. Chem. , 130, 5048–5049. , and Oshima, K. (2009) Bull. Chem. Soc. , 82, 393–400. H. (1957) J. Org. G. (1964) J. Am. Chem. , 86, 5043–5044. K. T. (1974) J. Am. Chem. , 96, 1508–1514. , and Turner, G. (1977) J. Chem. , 1576–1582. 70. Tsuji, J. and Ohno, K. (1969) Synthesis, 157–169. 71. M. E. (1971) J. Am. Chem. , 93, 5465–5468.

82, 393–400. H. (1957) J. Org. G. (1964) J. Am. Chem. , 86, 5043–5044. K. T. (1974) J. Am. Chem. , 96, 1508–1514. , and Turner, G. (1977) J. Chem. , 1576–1582. 70. Tsuji, J. and Ohno, K. (1969) Synthesis, 157–169. 71. M. E. (1971) J. Am. Chem. , 93, 5465–5468. 72. , Bergman, 73. 74. 75. 76. 77. 78. 79. 80. 81. 82. 83. 84. , and Brookhart, M. (2003) J. Am. Chem. , and Koga, N. , and Tobita, H. (2006) Organometallics, 25, 472–476. R. (1930) J. Am. Chem. , 52, 2083–2090; (b) Cohen, T. A. (1970) J.

Download PDF sample

Rated 4.70 of 5 – based on 21 votes