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By Gould R.F. (ed.)

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Extra resources for Bioinorganic Chemistry

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N. Lewis. They are the ones that are currently in most use by chemists, but the first one is specifically relevant to aqueous solutions. 1. 2 Bransted and Lowry Acids and Bases A is defined as a ,a . The definitions apply generally to as a can occur. 1) where AH represents a general acid with a dissociable proton and B represents a general base which can accept a proton. In the reverse process, where the proton is donated by the BHf ion to the anion A-, BH is called the of the base B and the anion A- is called of the acid AH.

For solvents, the definition of activity is the ratio of its vapour pressure when acting as a solvent, p , divided by the vapour pressure of the pure solvent, p", taken as the standard state: = 1. 7) to account for the non-ideal behavior of solutes and solvents. O. 11) where the quantities in square brackets are the concentrations of the indicated species compared to the standard concentration of 1 mol dm-3. 3. e. it purposes, completely dissociated. 99) indicates that the HS04- ion is not a particularly strong acid.

35) Multiplying the work of transfer by the Avogadro constant gives the molar change in Gibbs energy of hydration when c,. 54 at 25 "C). 86 x 104 x 1kJ mol-' 1'; when ri has units of picometres. 38) gives a value for the entropy change accompanying ion hydration as Ah)dS* = a

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